After that match gets things underway at 6.35am, Viktor Hovland and Ludvig Aberg face Max Homa and Brian Harman in a match containing three rookies, followed by Shane Lowry and Sepp Straka against Rickie Fowler and Collin Morikawa.
The morning lineup is completed by a European heavyweight pairing in Rory McIlroy and Tommy Fleetwood taking on Xander Schauffele and Patrick Cantlay.
Captain Luke Donald has changed Europe's opening strategy as he bids to extend their 30-year unbeaten home run against the United States.
The home side gets to choose whether to start Friday's first session with four foursomes or four fourballs matches, with the other format following in the afternoon session. Saturday sees two more sessions of the team matches before Sunday's 12 singles.
Europe have started with fourballs since 1997 but Donald said he had flipped things around after "a deep dive into statistics of the team".
